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The mechanism of such effect is not quite clear but the authors speculate that this behaviour relates with the capacity of endohedral fullerenes to “scavenge” reactive oxygen species. 30 K. H. Warner Apart from biomedical applications, another area where fullerenes in general have shown tremendous potential is optoelectronics. Empty cage fullerenes have already been used successfully in organic photovoltaic devices with an efficiency reaching 5% in polymer bulk-heterojunction devices . Endohedral metallofullerenes have higher electron affinity ( 3 eV) and lower ionisation potential ( 7 eV) than empty cages; hence they are better electron acceptors and better electron donors.
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